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template-fit
RadiaCode-Spectrometer/sample_test.xml
vhadmin 0820999776 Replace peak-search identification with full-spectrum template fitting 
The peak-search-and-gate pipeline had reached the point where each field
test added another veto, and vetoes only subtract sensitivity: ~28 tuned
constants and 6 boolean gates. Measured on the real uranium capture, it
was correct at 300s and 600s, wrong at 900s and 1200s, correct again at
1800s - more data made it worse.

Identification is now a Poisson maximum-likelihood fit of the whole
spectrum against per-nuclide response templates. Nuclides compete through
the likelihood, so the competitive-assignment, share-margin and
better-explained-elsewhere tie-breakers are gone, along with ~20 of the
constants. Detection is one threshold that means the same thing for every
nuclide: 3 sigma on a fitted amplitude.

Four things this needed, each found by measurement:
- 16 broad continuum bumps, not 4 exponentials. chi2 62 -> 3.3, and
  stopped nuclide templates being recruited as continuum filler.
- Full Fisher covariance, not the diagonal, which claimed Co-60 12.8
  sigma on background containing none.
- Chain-coupled columns at secular equilibrium. Six free U-238
  amplitudes let Tl-208 eat Bi-214's 609 keV line - the NATURAL MIX bug.
- FIT_MIN_KEV 150: the X-ray region is unmodelled, and Ba-133 scored 70%
  on real ore largely on its 81 keV line.

Also:
- spectrum_window: analysis runs on counts since a baseline that rolls
  forward on a confirmed rate step, so a source presented to a long
  accumulation is seen without pressing RESET.
- PSRAM was never actually enabled. BOARD_HAS_PSRAM alone does nothing;
  memory_type selects the sdkconfig. getPsramSize() was 0, the template
  matrix could not allocate, and analyzeSpectrum() silently fell back to
  the old path while looking perfectly healthy on serial.
- The fit no longer runs inside DataGuard. Holding the mutex for the
  1-3s fit blocked every draw and touch on core 1.
- BACKGROUND is no longer claimed after 120s. This ore needs ~600s, so
  the device announced "background" with a real source in front of it.
- quality.weakestKeySigma held the strongest sigma while labelled
  weakest, so grade, progress and "measurement complete" were all wrong.
- Chain members are listed as evidence (Pb-212/Tl-208/Ac-228) instead of
  one representative.
- DataGuard added to the UI screens that read g_data on core 1.

host/ is an offline replay harness that compiles the real analysis
sources against shims and replays captured spectra, with sweep and
presentation modes. host/spectra/ holds three real captures.

Verified on hardware: uranium ore identified at 5.0 sigma and held;
thorium mantle correct; WiFi/BLE coexistence measured across a full OTA
check with the fit resident.

Known: Eu-152 reads ~5.4 sigma on the ore - genuine template degeneracy
with Pb-214, not a threshold problem. Am-241 is no longer identifiable
below the fit range.
2026-09-01 14:02:32 +02:00

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<?xml version="1.0" encoding="utf-8"?>
<ResultDataFile><ResultDataList><ResultData><EnergySpectrum>
<NumberOfChannels>1024</NumberOfChannels>
<EnergyCalibration><Coefficients>
<Coefficient>3.839503</Coefficient><Coefficient>2.375420</Coefficient><Coefficient>0.000364</Coefficient>
</Coefficients></EnergyCalibration>
<MeasurementTime>600</MeasurementTime>
<Spectrum>
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